International Journal of Environmental Science and Technology

Volatile organic compounds emitted from hardwood drying as a function of processing parameters

*K. M. Granström; B. Månsson

During the drying of wood, volatile organic compounds are emitted. These emissions contribute, in the presence of nitrogen oxides and sunlight, to the formation of ground level ozone and other harmful photo-oxidants. Emissions of volatile organic compounds from the drying of birch sawdust in a spouted bed were analyzed with a flame ionization detector and with a gas chromatograph-mass pectrometer. A D-optimal model of the emissions showed that the emissions increased exponentially with decreasing sawdust moisture content and that the final sawdust moisture content was influencing emissions about twice as much as the inlet drying medium temperature and the month of logging. At inlet temperatures of 140-170 'C, the emissions increased steeply when the moisture content of the sawdust reached 10%, whereas an inlet temperature of 200 'C caused a surge of thermal degradation products at 15% moisture content. The results of this study should help to reduce the emissions of volatile hydrocarbons during the drying of hardwood sawdust and wood chips.

Flow and high sediment yield from the Huangfuchuan watershed

1*J. Sui; 2Y. He; 3B. W. Karney

This study deals with general features of sediment transport in the Huangfuchuan river, an important branch river of the Yellow river, draining the Loess Plateau in China. The long-term precipitation records at 3 climate stations near the watershed have been used to assess the changes in precipitation in this region. By introducing metrics for runoff and sediment transport, long-term observations on discharge and sediment concentration at the Huangfuchuan gauging station on the Huangfuchuan river have been used to assess the changes in runoff and sediment transport in the Huangfuchuan River compared with those at the Toudaoguai and Fugu gauging stations on the Yellow river. It is found that both runoff and sediment metrics have a clearly downward trend. From July to August, the long-term sediment transport modulus at the Huangfuchuan gauging station is much higher than those at the Toudaoguai and Fugu stations on the Yellow river. The long-term average sediment transport modulus at the Huangfuchuan gauging station are high, ranging from 14000. t/(km2 y) but decreasing to 5900 t/(km2 y) over the last 10 years . Additionally, analyses on grain size distribution of suspended load in the Huangfuchuan and Yellow river have been conducted.

Adsorption of hexavalent chromium from aqueous solutions by wheat bran

1M. Nameni; 1*M. R. Alavi Moghadam; 2M. Arami

In this research, adsorption of chromium (VI) ions on wheat bran has been studied through using batch adsorption techniques. The main objectives of this study are to 1) investigate the chromium adsorption from aqueous solution by wheat bran, 2) study the influence of contact time, pH, adsorbent dose and initial chromium concentration on adsorption process performance and 3) determine appropriate adsorption isotherm and kinetics parameters of chromium (VI) adsorption on wheat bran. The results of this study showed that adsorption of chromium by wheat bran reached to equilibrium after 60 min and after that a little change of chromium removal efficiency was observed. Higher chromium adsorption was observed at lower pHs, and maximum chromium removal (87.8 %) obtained at pH of 2. The adsorption of chromium by wheat bran decreased at the higher initial chromium concentration and lower adsorbent doses. The obtained results showed that the adsorption of chromium (VI) by wheat bran follows Langmuir isotherm equation with a correlation coefficient equal to 0.997. In addition, the kinetics of the adsorption process follows the pseudo second-order kinetics model with a rate constant value of 0.131 g/mg.min The results indicate that wheat bran can be employed as a low cost alternative to commercial adsorbents in the removal of chromium (VI) from water and wastewater.

Evaluation of land farming and chemico-biological stabilization for treatment of heavily contaminated sediments in a tropical environment

*R. H. Adams; F. J. Guzmán-Osorio

Conventional and experimental methods were studied for the remediation of petroleum contaminated sediments from a dam previously used to collect acid run-off from a sulfur mine. The man-made lake had been neutralized, but bentonite rich sediments remained contaminated with very weathered hydrocarbons (sediments with ~50,000-60,000 mg/kg Total Petroleum Hydrocarbons were used in this study). Biostimulation, bioaugmentation (with native microorganisms) and chemico-biological stabilization, all resulted in similar reductions (14-16%) in the TPH concentration over a three month period. The land farming treatments resulted in variable reductions in toxicity, ranging from nil to complete, while the chemico-biological stabilization treatment, not only eliminated acute toxicity but also resulted in a slight stimulation (~103-109%) of the test organism in the bioassay (Microtox). All three treatments reduced polyaromatic hydrocarbons of probable carcinogenicity to below or nearly below the Mexican norms, reduced Toxic Characteristic Leaching Proceedure leachates to <1 mg/L, and left the material in a pH range of 7.0-7.8. The chemico-biological stabilization has the advantage of only requiring initial mixing of the chemical and organic reagents instead of daily aeration, thereby reducing operating costs. This method is also able to treat very difficult sites at low cost, relying on biological humification processes which are accelerated in a humid tropical and semitropical environment. The total unit cost of the chemico-biological stabilization treatment was estimated to be ~60% of that for land farming in the southern Gulf of Mexico region.

Bioaccumulation of heavy metals in organs of fresh water fish Cyprinus carpio (Common carp)

*R. Vinodhini; M. Narayanan

The objective of the present study is to determine the bioaccumulation of heavy metals in various organs of the fresh water fish exposed to heavy metal contaminated water system. The experimental fish was exposed to Cr, Ni, Cd and Pb at sublethal concentrations for periods of 32 days. The elements Cd, Pb, Ni and Cr were assayed using Shimadzu AA 6200 atomic absorption spectrophotometery and the results were given as µg/g dry wt. The accumulation of heavy metal gradually increases in liver during the heavy metal exposure period. All the results were statistically significant at p < 0.001. The order of heavy metal accumulation in the gills and liver was Cd > Pb > Ni > Cr and Pb > Cd > Ni > Cr. Similarly, in case of kidney and flesh tissues, the order was Pb > Cd > Cr > Ni and Pb > Cr > Cd > Ni. In all heavy metals, the bioaccumulation of lead and cadmium proportion was significantly increased in the tissues of Cyprinus carpio (Common carp).

An environmental oriented model for optimum cut-off grades in open pit mining projects to minimize acid mine drainage

1*F. Rashidinejad; 2M. Osanloo; 2B. Rezai

Environmental concerns on mining activities started near the end of the 20th century and is still underway. Due to mining activities, the adverse environmental impact has been significant throughout the history of mankind, whereas the minerals produced by mining activities have been providing the basis for human civilization. The legacy of past mining practices is large quantities of acid generating waste materials and tailings that caused abounding acid mine drainage problems. Modern mining environmental management tends to focus on concerns over the impact of waste disposal on surface primarily in the form of tailings and waste materials structures. Sustainable development principles are being increasingly applied by mining companies in developed and developing countries. Operating costs per unit of operation is recognized to be one the most important sustainable mining practice indicator and cut-off grade is considered to be a well-founded representative for this indicator. In this study, a developed model for optimum cut off grades is presented that not only relies on economical aspects but also minimizes adverse environmental impact in the form of acid mine drainage elimination or mitigation against the approach of postponing the restoration/reclamation activities at the end of the project's life.

Multicriteria decision analysis in water resources management: the malnichara channel improvement

1*R. K. Chowdhury; 2R. Rahman

Multicriteria decision analysis tool is used in many water resources and environmental management projects. The Malnichara is one of the natural channels in Sylhet city (Bangladesh) responsible for storm runoff conveyance to the downstream Surma river. The channel is found to be encroached at many locations of the city and found to be very vulnerable. The authority has taken decision to improve natural channels by a traditional approach, e.g. constructing box culvert. In most cases, stakeholders' participation is ignored in such type of decision making. Hence, efforts were made to evaluate three common alternatives viz. sodding natural channel, lined natural channel and box culvert for the channel improvement. The channel is hydrologically divided into two parts: the upper portion (Choukidekhi-Kanishail) and the lower portion (Kanishail-Topoban). Both parts were separately analyzed. Small groups of stakeholders were interviewed for the selection of criteria and for the assignment of weighed factor and scores. Experts' opinions were also taken through consultation. Nine criteria from four categories such as technical, economic, environment and social aspects were selected. The relative performances of alternatives were evaluated using the weighed sum technique of multicriteria decision analysis. It was found that the sodding natural channel is the best alternative for both portions of the channel. However, the choice is very sensitive to the social criteria.

Green supply chain management in the electronic industry

*C. W. Hsu; A. H. Hu

Green supply chain management has emerged as a proactive approach for improving environmental performance of processes and products in accordance with the requirements of environmental regulations. Various approaches for implementing green supply chain management practices has been proposed and recognized in previous literatures, yet no investigation has identified the reliability and validity of such approaches particularly in electronic industry. This study examines the consistency approaches by factor analysis that determines the adoption and implementation of green supply chain management in Taiwanese electronic industry. The fuzzy analytic hierarchy process method is applied to prioritize the relative importance of four dimensions and twenty approaches among nine enterprises in electronic industry. The findings indicate that these enterprises would emphasize on supplier management performance in the crucial role of implementing green supply chain management. Establishing an environmental database of products, asking for product testing report and top management support are among the most important approaches. The results for the implications of green supply chain management implementation in electronic industry investigated in this work generate a generic hierarchy model for decision-makers who can prioritize those approaches for implementing green supply chain management in Taiwan.

Pb and Co removal from paint industries effluent using wood ash

1M. Malakootian, 2*A . Almasi, 1H. Hossaini

The release of heavy metals into the environment is a worldwide major concern. Different studies have demonstrated that natural agents have a high removal capacity for divalent heavy metal ions. Wood ash is a natural adsorbent and, in comparison with others, has a very low price. In this study, the removal of heavy metals (Pb and Co) from Binalood paint industry (Kerman, Iran) effluent was investigated in batch condition. Pb and Co measurement in samples were done with atomic absorption equipment and test methods were adapted from standard methods for the examination of water and wastewater. The effect of pH and the amount of adsorbent was determined and different adsorption isotherms were also obtained. This study shows that the adsorption process follows the adsorption Langmuir isotherm. The amount of wood ash has a great role in the adsorption rate and adsorption rate increased as wood ash increased. In the study, the reactions reached equilibrium in 3 h contact time. The maximum Pb removal efficiency was 96.1% at pH 2 with a contact time of 3 h and 100 g/L wood ash and the maximum Co removal efficiency was 99 % at pH 2 with a contact time of 3 h and 100 g/L wood ash. According to the results, wood ash is recommended as a low cost and available adsorbent to remove Pb and Co from municipal and industrial wastewaters.

Kinetics of batch microbial degradation of phenols by indigenous Pseudomonas fluorescence

1*S. E. Agarry; 2B. O. Solomon

The potential of various organisms to metabolize organic compounds has been observed to be a potentially effective means in disposing of hazardous and toxic wastes. Phenols and their compounds have long been recognized as one of the most recalcitrant and persistent organic chemicals in the environment. The bioremediation potential of an indigenous Pseudomonas fluorescence was studied in batch culture using synthetic phenol in water in the concentration range of (100 -500) mg/L as a model limiting substrate. The effect of initial phenol concentration on the degradation process was investigated. Phenol was completely degraded at different cultivation times for the different initial phenol concentrations. Increasing the initial phenol concentration from 100 mg/L to 500 mg/L increased the lag phase from 0 to 66 h and correspondingly prolonged the degradation process from 84 h to 354 h. There was decrease in biodegradation rate as initial phenol concentration increased. Fitting data into Monod kinetic model showed the inhibition effect of phenol The kinetic parameters have been estimated up to initial phenol concentration of 500 mg/L. The rsmax decreased and Ks increased with higher concentration of phenol. The rsmax has been found to be a strong function of initial phenol concentration. The culture followed substrate inhibition kinetics and the specific phenol consumption rates were fitted to Haldane, Yano and Koga, Aiba et al., Teissier and Webb models. Between the five inhibition models, the Haldane model was found to give the best fit. Therefore, the biokinetic constants estimated using these models showed good potential of the Pseudomonas fluorescence and the possibility of using it in bioremediation of phenol waste effluents.

Oil spill sorption using carbonized pith bagasse: trial for practical application

1M. Hussein; 2*A. A. Amer, 2 I. I. Sawsan

In the present work, an attempt was made to provide an efficient, easily deployable method of cleaning up oil spills and recovering of the oil. Carbonized pith bagasse, a relatively abundant and inexpensive material is currently being investigated as an adsorbent to remove contaminants 'oil' from water. Fibers extracted from bagasse and carbonized at 300 'C were found to have a high performance for sorption and recovery of light, heavy oils and even the viscous ones. The physical properties of pith bagasse were investigated using scanning electronic microscope to show the inner and the outer surface and the cross section area of the pith bagasse and thermo gravimetric analyzer to investigate the degradation profile of the pith bagasse. The carbonized pith bagasse was packed into a polypropylene bag and its sorption behavior was studied. A comparison was made between the prepared pad and the commercial sorbents show that the pad containing carbonized pith bagasse has higher sorption capacity in comparison to the commercial sorbents. The pad exhibited high oil retention ability and a high selectivity for the oils over the water. The pad showed a possibility of reuse for eight times. The sorption capacity of the pads containing carbonized pith bagasse was found to increase with increasing the time of sorption till it reaches the maximum value at the time of sorption equal to 60 min.

Assessment of the physicochemical parameters and heavy metals toxicity of leachates from municipal solid waste open dumpsite

1O. O. Ogundiran; 2*T. A. Afolabi

Heavy metals and physicochemical characteristics of the different sites of the municipal solid waste dumpsite at Olusosun Landfill, Lagos, Nigeria, were investigated. The dormant site of the landfill has the potential of being a source of immediate environmental risk compared to the active and abandoned site, with the active site exhibiting tendency to be a likely source of Pb, Cd and Zn pollution. Zn was the most abundant metal in the area (0.264-0.947 mg/L) while Cd concentration was the lowest (0.001-0.022 mg/L). Pb, Cd, Zn were from anthropogenic sources and correlated significantly with chemical oxygen demand and oil and grease. Cu and Cr were more abundant in the dormant site and are attached to the solids as indicated by their significant correlation with TS and SS. The physicochemical characteristic of the leachate from the landfill indicate that they were more alkaline in nature, with TA range of 2354 to 7946 mg/L while the chemical oxygen demand values was also high 518.14 to 725.01 mg/L. The comparative analysis of the dormant site with other dormant site reveal a moderate concentration of the parameters measured but could contaminate the neighboring groundwater if not checked.

Application of an environmentally optimum cooling water system design in water and energy conservation

M. H. Panjeshahi; *A. Ataei

Recirculating cooling water systems are consist of a cooling tower and heat-exchanger network which conventionally have a parallel configuration. However, reuse of water between different cooling duties enables cooling water networks to be designed with series arrangements. This will results in performance improvement and increased cooling tower capacity. Research on recirculating cooling water systems has mostly focused on the individual components. However, a particular design method represented by Kim and Smith accounts for the whole system interactions. In this study, the Kim and Smith design method is expanded and a comprehensive simulation model of recirculating cooling system was developed to account for the interaction between the cooling tower performance and the heat-exchanger network configuration. Regarding this model and considering cycle water quality through introducing ozone treatment technology, a modern methodology of recirculating cooling water system design was established and developed. This technique, called the integrated ozone treatment cooling system design, is a superior designed tool based on pinch analysis and mathematical programing. It also ensures maximum water and energy conservation, minimum cost and environmental impacts. Related coding in MATLAB version 7.3 was used for the illustrative example to get optimal values in cooling water design method computations. The result of the recently introduced design methodology was compared with the Kim and Smith design method.

Concentration of uranium levels in groundwater

The uranium isotopes during their course of their disintegration decay into other radioactive elements and eventually decay into stable lead isotopes. The cause of environmental concern is the emanation of beta and gamma radiation during disintegration. The present study tends to estimate uranium in groundwater trapped in granite and gneiss rocks. Besides, the study aims at estimating the radiation during natural disintegration process. The water samples were collected and analyzed following inductively coupled plasma mass spectrometric technique while water sample collection was given to the regions of Kolar District, South India, due to the representation. The significant finding was the observation of very high levels of uranium in groundwater compared to similar assays reported at other nearby districts. Also, the levels were considerable to those compared to groundwater levels of uranium reported by other scientists. On the basis of this study, it was inferred that the origin of uranium was from granite strata and there was a trend of diffusion observed in the course of flow-path of water in the region.

Sulphate reducing bacteria to precipitate mercury after electrokinetic soil remediation

1T. Håkansson, 2*P. Suer, 1B. Mattiasson, 3B. Allard

Combined treatment with electroremediation and sulphate reducing bacteria (SRB) was tested in laboratory and pilot scale. The contaminated soil came from a chlor-alkali factory and contained about 100 mg/kg Hg. Iodide/iodine complexing agent was used to mobilize mercury. Mercury iodide complexes were moved to the anode solution using an electric field. The anode solution was then mixed with hydrogen sulphide (H2S) containing water, causing precipitation of mercury sulphide. The H2S was produced at site by a SRB reactor. Precipitation problems arising from the nature of the anode solution were expected, since this solution is highly acidic, very oxidised and may contain iodide/iodine that strongly complexes mercury and can hinder mercury sulphide precipitation. Mercury concentrations in the anode solution were up to 65.7 mg/L (field) and 15.4 mg/L (lab. scale). Reduction of mercury in the water was >93% at all times. Iodide did not hinder the process: Nonetheless, in the lab system, iodide concentration was high in the anode solution but mercury reduction was > 99.9%. The redox potential was sufficiently low for HgS precipitation during the experiments, except for a short period, when the mercury removal decreased to 94%. Sulphate reducing bacteria are shown as a viable tool for the treatment of mercury contaminated, acidic, oxidative, iodide containing water, such as that produced by electrokinetic remediation. A second SRB step or other water treatment is required to reduce the mercury concentration to environmentally acceptable levels. Redox potential is the most sensitive factor in the system.

Application of agricultural fibers in pollution removal from aqueous solution

*A. H. Mahvi

Discharging different kinds of wastewater and polluted waters such as domestic, industrial and agricultural wastewaters into environment, especially to surface water, can cause heavy pollution of this body sources. With regard to increasing effluent discharge standards to the environment, high considerations should be made when selecting proper treatment processes. Any of chemical, biological and physical treatment processes have its own advantages and disadvantages. It should be kept in mind that economical aspects are important, too. In addition, employing environment-friendly methods for treatment is emphasized much more these days. Application of some waste products that could help in this regard, in addition to reuse of these waste materials, can be an advantage. Agricultural fibers are agricultural wastes and are generated in high amounts. The majority of such materials is generated in developing countries and, since they are very cheap, they can be employed as biosorbents in water and wastewater applications. Polluted surface waters, different wastewaters and partially treated wastewater may be contaminated by heavy metals or some organic matters and these waters should be treated to reduce pollution. The results of investigations show high efficiency of agricultural fibers in heavy metal and phenol removal. In this paper, some studies conducted by the author of this article and other investigators are reviewed.